In contrast, prior to annealing even such small fept nanoparticles did not show a welldefined orientation relationship with mgo substrates, and, in. We recently demonstrated that using selfassembly of two different magnetic nanoparticles, fept and fe3o4, followed by reductive annealing to remove organic surfactant around each. Magnetic properties of fept nanoparticles prepared by. Inhomogeneous alloying in fept nanoparticles as a reason. Fept nanoparticles nps are a diverse class of magnetic nps, which exhibit attractive properties for potential applications, from high density data storage devices to biomedical applications. This renders them potential candidates for application in spintronic devices, magnetic sensing and ultrahigh density data storage 114. Synthesis, chemical ordering, and magnetic properties of feptcu nanoparticle. Monodisperse fept nanoparticles and ferromagnetic fept nanocrystal superlattices shouheng sun,1 c.
Nanoseparation was performed on ironplatinum based nanoparticles from the reaction between ironiii tris2,2,6,6tetramethyl3,5heptanedionate and platinumii acetylacetonate. Onestep synthesis of fept nanoparticles with tunable size. Colloidal syntheses of fept nanoparticles 41 fept is a bimetallic alloy material comprised of both iron and platinum. New approach to fully ordered fct fept nanoparticles for much enhanced electrocatalysis in acid qing li.
The fept nanoparticles exhibit clearly defined facets and are wellbond to the substrate with a special orientation relation. Fept nanoparticles have practical potential in fields as diverse as catalysis and magnetic storage media. New approach to fully ordered fctfept nanoparticles for. Monodisperse fept nanoparticles and ferromagnetic fept. Silicide induced surface defects in fept nanoparticle fcc. Orientation of fept nanoparticles on top of asio2si001. At the carbon k edge, the spectra were normalized to the absorption signal of a clean substrate. Sonoelectrodeposition is a useful technique to make metallic nanoparticles, using ultrasound during electrodeposition to remove nanoparticles as they grow on the cathode surface. Functionalized with luteinizing hormonereleasing hormone lhrh peptide via phospholipid, the fcc fept nps can bind. Fept nanoparticles as an fe reservoir for controlled fe. The fept nanoparticles were dispersed in 6 ml of octane and stored in a brown glass bottle under the nitrogen conditions. The al2o3 substrates were functionalized with aminobutylphosphonic acid abp or.
Motivation nanostructured fept has potential applications in magnetic storage. Fept nanoparticles nps were assembled on aluminum oxide substrates, and their ferromagnetic properties were studied before and after thermal annealing. Fept nanoparticles were obtained by repeating the separation process for 23 times. The hysteresis loops of randomly oriented assembly of fept nanoparticles are calculated numerically as a function of particle diameter for the range of the effective anisotropy constants, kef 1510e7 ergcm3, taking into account the effect of.
Fept nanoparticle cores were synthesized following a previously published protocol 6. Synthesis, characterization and potential applications of fept nanoparticles. The synthesis originally described by sun and coworkers yields monodisperse nanoparticles that have the a1 structure. The 8001 diffraction ring is hard to discern because it is too close to the central direct beam. For comparison study, we also prepared the control samples of fept nanoparticles using the same processing without an applied magnetic field. Niklesa center for materials for information technology, the university of alabama, tuscaloosa. The asprepared fe 45 pt 55 nanoparticles were ferromagnetic at room temperature. Review article recent advances in fept nanoparticles for. Dynamic light scattering dls provided a rapid and effective technique to monitor the classification of these polydisperse nanoparticles. Controlled synthesis and assembly of fept nanoparticles. Synthesis and characteristics of fept nanoparticle films. Silicide induced surface defects in fept nanoparticle fcctofct thermally activated phase transition shu chen,a stephen l. Harrell, gregory thompson, and gary mankey center for materials for information technology, the university of alabama, tuscaloosa.
Synthesis of monodisperse ironplatinum fept nanoparticles by reduction of platinum acetylacetonate and decomposition of iron pentacarbonyl in the presence of oleic acid and oleyl amine stabilizers is reported. We report a promising strategy to directly synthesize l10 fept nanoparticles for applications in permanent magnets and catalysts. Films of fept nanoparticles nps embedded in mgo were obtained by controlled codeposition of fept nps preformed by a gas aggregation source and of mg evaporated in an oxygen atmosphere. Pdf effective magnetic anisotropy of annealed fept. The preparation technique employed allows to anneal sinter the particles in the gasphase prior to their deposition.
In situ external magnetic field was applied during the synthesis of fept nanoparticles via a chemical solution method. These fct fept nps show strong ferromagnetism with room temperature coercivity reaching 33 koe. For the first time, phosphonates were used as an adsorbate to form selfassembled monolayers sams on alumina to direct the assembly of nps onto the surface. Recently, ferromagnetic nanoparticles fept nps have attracted interest due to their high chemical stability, magnetic properties and small size. Sintering behavior of spincoated fept and feptau nanoparticles shishou kang,a zhiyong jia, i. Monolayerdirected assembly and magnetic properties of. Monodisperse fept nanoparticles and ferromagnetic fept nanocrystal superlattices article pdf available in science 2875460. It has relatively high curie temperature, tc 750 k table 1, which is much. Dynamic light scattering and image analysis of fept based. Pdf monodisperse fept nanoparticles and ferromagnetic. Interestingly, the type of atmosphere ar or arh2 and the size of selected fept. Neutron pair distribution function analysis and 3d. Synthesis, characterization and applications 33 two pot synthesis of hydrophilic fept nanoparticles for the synthesis, the precursors, platinum ii acetylacetonate pt acac2, oleic acid c18h34o2 and oleylamine c18h37n were procured from sigmaaldrich. Fept nanoparticles have great potential for biomedical applications due to their superior characteristics, including superparamagnetism, resistance to oxidation, and high chemical stability.
The fept nanoparticles have been synthesized by mixing two precursor liquids. Recent advances in fept nanoparticles for biomedicine. A quantitative fluorescence study of protein monolayer. The effect of in situapplied magnetic field on the structure. Direct synthesis of l10fept nanoparticles with high. Controlled codeposition of fept nanoparticles embedded in. As can be seen in the image, the selfassembled fct fept nanoparticles form chains along the magnetic. Additionally, using a simple model to capture the thermal behavior, we predict that a fivelayered nanoparticle with approximately 700 atoms can be expected to be useful in magnetic recording applications at room temperature. Synthesis of fept nanocubes and their oriented selfassembly. Magnetic properties of fept nanoparticles sciencedirect. The present work describes an abiotic energy harvesting strategy from electrocatalytic glucose oxidation based on bimetallic fept nanoparticles nps with a unique onset oxidation potential of. Preventing surface oxidation of the ni seeds is essential for the growth of uniform fept shells. Chemically disordered face centered cubic fcc fept nanoparticles nps show the controlled release of fe in low ph solution.
The released fe catalyzes h2o2 decomposition into reactive oxygen species within cells, causing fast oxidation and deterioration of cellular membranes. The typical secondary growth of au proceeded in the presence of fept seeds in organic solvents under a specific atmosphere. Effect of oleic acid and oleylamine surfactants on the. We report an effective and facile method for synthesis of fept au hybrid nanoparticles hnps. The size, composition, and shape of the particles are controlled by varying the synthetic parameters such as molar ratio of stabilizers to metal precursor, addition sequence of the stabilizers and metal precursors, heating. Synthesis, characterization and potential applications of.
By repeating the coating of pei and fept, the multilayer of 4 nm fept nanoparticle assembly was easily made. Microstructures and magnetic alignment of l10 fept. Chemically synthesized fept nanoparticles have received considerable attention in recent years because of their potential for ultrahigh density data storage. Controlled synthesis of feptau hybrid nanoparticles. Ironplatinum nanoparticles fept nps are 3d superlattices composed of an approximately equal atomic ratio of fe and pt. Under standard conditions, fept nps exist in the facecentered cubic phase but can change to a chemically ordered facecentered tetragonal phase as a result of thermal annealing. The particle structure and morphology depend strongly on the details of the preparation process. The physical properties of fept nps are also of speci c interest for these applications, as they.
Magnetic properties of fept nanoparticles request pdf. The effect of in situapplied magnetic field on the structure, morphology, and magnetic properties of fept nanoparticle films was characterized. We report synthesis and characterization of bimagnetic coreshell fept fe3o4 nanoparticles with fept core being 4 nm and shell fe3o4 tunable from 0. After the sizeselective precipitation, the nanoparticles were separated. We would like to show you a description here but the site wont allow us. Fept magnetic nanoparticles have been synthesized by superhydride reduction of fecl2 and ptacac2 at high temperature. To render them water soluble, they were coated with an amphiphilic polymer synthesized from. Adding superhydride libet3h to the phenyl ether solution of fecl2 and ptacac2 in the presence of oleic acid, oleylamine, and 1,2hexadecanediol at 190.
Review article recent advances in fept nanoparticles for biomedicine yujuanshi, 1,2 meilin, 1 xingmaojiang, 3 andshuailiang 3 taizhou people s hospital aliated to nantong university, no. Murray,1 dieter weller,2 liesl folks,2 andreas moser2 synthesis of monodisperse ironplatinum fept nanoparticles by reduction of. We have recently shown that fept nanoparticles can be prepared by means of a gasphasebased technique that allows to anneal sinter the particles prior to being deposited onto a substrate. Fept nanoparticles are candidate for developing ultra high density magnetic media. The element pb with lower melting point, smaller surface energy, and a bigger atomic radius can improve migration of fe and pt atoms and promote orderly diffusion in the l10 fept nanoparticles by generating vacancies and lattice distortion. The fept particle composition is readily controlled, and the size is tunable from 3 to 10nanometer diameter with a standard deviation of less than 5%.
In searching for shapecontrolled synthesis of fept nanoparticles, we found that simultaneous decomposition of feco5 and reduction of ptacac2 without polyol as a reducing agent yielded fept nanoparticles with sizes tunable from 3 to 9 nm. Using dualfocus fluorescence correlation spectroscopy, we have analyzed the adsorption of three human blood serum proteins, namely serum albumin, apolipoprotein ai and apolipoprotein e4, onto polymercoated, fluorescently labeled fept nanoparticles 12 nm diameter carrying negatively charged carboxyl groups on their surface. The site provides a crosssearch function for accessing treatises in the field of steel technology, a database of report abstracts from the main steel and steelrelated journals, links to the principle journals and steel company technical reports, as well as links to steelrelated news and. This paper reports some structural and magnetic properties of fept nanoparticles prepared by this method. But far from being pristine crystalline materials, these nanoparticles are structurally. Monodisperse coreshell nifept nanoparticles and their. They serve as a robust electrocatalyst for the oxygen reduction reaction orr in 0. Steel science portal is a website for accessing the latest information about steelrelated technology. A onestep synthesis of fept nanoparticles is reported. Fully ordered facecentered tetragonal fct fept nanoparticles nps are synthesized by thermal annealing of the mgocoated dumbbelllike fept fe3o4 nps followed by acid washing to remove mgo. We have prepared fept nanoparticles with concentrations in the vicinity of the stoichiometric fe 50 pt 50 composition by means of a gasphasebased process.